端口不NAT，两个子网中的两端之间不可能通信。至少要有一方处在公网下或有路由端口映射，不必双方都映射。
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建议题主找本计算机网络的书研读一下子网划分这块儿。
传输Integer 数据类型来传输比较方便.因为Integer 的取值可以是0x0000-0xFFFF .当你把数据发送到目的主机后可以利用Hex() 把接收到的数据从十进制转换到十六进制..
用 vb.net socket通信
Dim th As Threading.Thread
2 Dim tcpl As System.Net.Sockets.TcpListener
3
4 Private Sub Form1_Load()Sub Form1_Load(ByVal sender As System.Object, ByVal e As System.EventArgs) Handles MyBase.Load
5 th = New System.Threading.Thread(New System.Threading.ThreadStart(AddressOf MyListen))
6 th.Start()
7 End Sub
8
9 Public Sub SendMessage()Sub SendMessage(ByVal IP As String, ByVal SendMsg As String)
10 Try
11 If IP "" Then
12 Dim tcpc As New System.Net.Sockets.TcpClient(IP, 5656)
13 Dim tcpStream As Net.Sockets.NetworkStream = tcpc.GetStream
14 Dim reqStream As New IO.StreamWriter(tcpStream)
15 reqStream.Write(SendMsg)
16 reqStream.Flush()
17 tcpStream.Close()
18 tcpc.Close()
19 End If
20 Catch ex As Exception
21 MsgBox(ex.Message.ToString)
22 End Try
23 End Sub
24 Private Sub MyListen()Sub MyListen()
25 Try
26 Dim ipAddress As System.Net.IPAddress = System.Net.Dns.Resolve(System.Net.Dns.GetHostName).AddressList(0)
27 tcpl = New System.Net.Sockets.TcpListener(ipAddress, 5656)
28 tcpl.Start()
29 While True
30 Dim s As System.Net.Sockets.Socket = tcpl.AcceptSocket()
31 Dim MyBuffer(1024) As Byte
32 Dim i As Integer
33 i = s.Receive(MyBuffer)
34 If i 0 Then
35 Dim lstrRec As String
36 Dim j As Integer
37 For j = 0 To i - 1
38 TextBox1.Text += Chr(MyBuffer(j)) ","
39 Next
40 End If
41 End While
42 Catch ex As Exception
43 MsgBox(ex.Message.ToString)
44 End Try
45 End Sub
46
47 Private Sub Button1_Click()Sub Button1_Click(ByVal sender As System.Object, ByVal e As System.EventArgs) Handles Button1.Click
48 SendMessage("192.168.0.61", TextBox2.Text)
49 End Sub
